ArticleACS omega2026
Room-Temperature Columnar Liquid Crystals from Hydrogen-Bonded Dendritic Assemblies.
Article in ACS omega, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Authors and funding
3 authors.
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Abstract
Dendrimers represent a distinctive class of synthetic macromolecules with broad utility across soft matter, materials science, nanotechnology, and biomedical sciences. In this study, we describe the synthesis of carboxylic acid-functionalized first and second-generation dendrimers using CuAAC (copper-catalyzed azide, alkyne cycloaddition) click chemistry. Dendrimers exhibit thermotropic mesomorphic behavior and form robust hydrogen-bonded supramolecular complexes with benzotriazole or benzimidazole derivatives. Notably, the hydrogen-bonded complexes also exhibit mesomorphism. Interestingly, some of these exhibit a room-temperature columnar hexagonal mesophase and transition to cubic phases. By underscoring the pivotal role of noncovalent interactions in modulating liquid-crystalline order, this work provides a systematic investigation of the mesomorphic properties of all of the newly synthesized dendrimers and their supramolecular assemblies.
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Registered trials
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