ArticleAngewandte Chemie (International ed. in English)2026
Record Dissymmetry in Vibrational Optical Activity: Combining Vibronic Coupling and Aggregation in Cobalt(II) Camphorate Complexes.
Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
A family of cobalt(II) bis-trifluoroacetylcamphorate complexes (1-3), along with the diamagnetic zinc(II) analog 4, has been synthesized and structurally characterized. The cobalt complexes exhibit solvent-driven interconversion between cis- and trans-octahedral geometries, coupled to labile solvent coordination. Their chiroptical response spans the UV, visible, NIR, and IR ranges and is highly sensitive to coordination geometry and solvent. In dilute solutions, vibrational circular dichroism (VCD) dissymmetry factors up to |g| ≈4 × 10
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