ArticleACS applied polymer materials2026
Alginate Aerogels Crosslinked with Isophorone-Based Polyurea: The Missing Link between Rigid Aromatic and Flexible Aliphatic Nanostructured Networks.
Article in ACS applied polymer materials, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Polyurea-cross-linked alginate (X-Ca-alg-IP) aerogels, prepared from calcium alginate (Ca-alg) gels and the isocyanurate trimer of rigid aliphatic isophorone diisocyanate (IP), provide insight into the role of the cross-linker molecular structure in the nanoscale and macroscopic properties of X-biopolymer aerogels. Keeping all other synthetic conditions the same, the polyurea (PUA) loading in X-Ca-alg-IP (40-46% w/w) was lower than what was obtained using flexible aliphatic (56% w/w) or rigid aromatic (60% w/w) triisocyanate monomers, reflecting differences in monomer reactivity and packing efficiency of the resulting PUA. Cross-linking preserved the macro/mesoporous nanoscale architecture of the native Ca-alg backbone, maintaining high porosity (up to 95% v/v) and specific surface area (up to 393 m
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