ArticleACS applied polymer materials2026
Vapor-Phase Deposition of Electroactive Polymers onto Electrospun Commodity Polyacrylonitrile Nanofibers.
Article in ACS applied polymer materials, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Electroactive polymers (EAPs) offer unique electrical and mechanical properties suitable for energy, environmental, and biomedical applications. Integrating EAPs with nanofibrous substrates can further enhance performance through the high surface area, interconnected porosity, mechanical flexibility, and tunable morphology of electrospun nanofibers. However, achieving uniform integration of EAPs on high-aspect-ratio nanofibers remains challenging due to poor coating homogeneity, limited penetration, and the reliance on toxic solvents in conventional deposition techniques. Here, a solvent-free vapor-phase deposition (VPD) process was developed to produce environmentally friendly and tunable EAP coatings on electrospun polyacrylonitrile (PAN) nanofibers. Electrospinning conditions were optimized to produce uniform PAN nanofibers with an average diameter of 350 nm. Poly-(3,4-ethylenedioxythiophene) (PEDOT), polypyrrole (PPy), poly-(3-hexylthiophene) (P3HT), and poly-(2,2'-bithiophene) (PBTH) were deposited via oxidative vapor-phase polymerization using iron-(III) chloride (FeCl
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