ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2026
Flame Suppression in Lithium-Ion Batteries During Thermal Runaway Through Solvent Design Considering the Volatility-Flammability Relationship.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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13 authors.
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Abstract
An asymmetric sulfonate-based linear solvent, 2,2,2-trifluoromethyl mesylate (FMS), is designed and used as the primary solvent in liquid electrolytes to enhance the thermal safety of lithium-ion batteries (LIBs). The highly polar FMS molecule, composed of trifluoroethyl and methyl groups asymmetrically bound to a sulfonate core, significantly suppresses solvent vaporization and shows a significantly higher flash point than the conventional LIB solvent dimethyl carbonate. Low volatility contributes to the non-flammability of the FMS electrolyte. Upon electrochemical cycling, the FMS-based electrolyte facilitates the formation of thermally stable SO
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