ArticleNature nanotechnology2026
Hydration layer mediates near-frictionless sieving of monovalent ions.
Article in Nature nanotechnology, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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16 authors.
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Abstract
Achieving simultaneous high selectivity and permeability for monovalent cation separation remains challenging due to energy-intensive dehydration requirements in current rigid nanopores. Here we develop a hydration-layer-mediated sieving strategy by anchoring hydrated ions at the pore rim of a covalent organic framework monolayer to form dynamic angstrom-scale hydrapores. Ion transport is regulated via attraction and repulsion between bound and migrating ions, arising from the merging and squeezing of hydration layers, enabling precise discrimination without full dehydration. Under a concentration gradient (∆C = 1 M), the membrane exhibits selectivity of 148 for K
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