ArticleInorganic chemistry2026
Anderson-Type Polyoxotungstate with Central Ruthenium, [RuIVW6O24]8-: Synthesis, Structure, Redox Studies, and Electrochemical Water Oxidation Activity.
Article in Inorganic chemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The reaction of Na2WO4·2H2O with [(benzene)RuCl2]2 at temperatures above 70 °C produced an Anderson-type ruthenotungstate, Na8[RuIVW6O24], together with (benzene)Ru-tungstates, [{(benzene)Ru}4W2O10] and Na6[{(benzene)Ru}2H2W8O30]. The first ruthenium-containing Anderson-type polyoxometalate was isolated by recrystallization and characterized using single-crystal X-ray diffraction (XRD), elemental analysis, powder XRD, infrared (IR) spectroscopy, thermogravimetry-differential thermal analysis (TG-DTA), X-ray absorption fine structure (XAFS), and cyclic voltammetry. Notably, Na8[RuIVW6O24] could only be synthesized using [(benzene)RuCl2]2; other ruthenium sources, such as RuCl3, Ru(DMSO)4Cl2, Ru(acac)3, and K2RuCl5(H2O), did not yield Na8[RuIVW6O24] under the same conditions. Cyclic voltammetry measurements revealed that the RuIV ions in Na8[RuIVW6O24] undergo a quasi-reversible one-electron redox process, RuIV/III. Furthermore, Na8[RuIVW6O24] demonstrates catalytic performance in water oxidation reactions, significantly outperforming the catalytic activity of Na6[{(benzene)Ru}2H2W8O30] and [{(benzene)Ru}4W2O10] complexes, highlighting its potential as an efficient catalyst for energy conversion processes.
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