Evidence map›Paper›PMID 42595742›Full record

ArticleChemSusChem2026

3A Cyanide-Bridged Ru-Fe Supramolecular Photocatalyst for Efficient CO

Francesca Mancini, Alberto Bianco, Albert Ruggi, Giacomo Bergamini

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in ChemSusChem, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Francesca ManciniDepartment of Chemistry "Giacomo Ciamician", University of Bologna, Bologna, Italy.ORCID https://orcid.org/0009-0000-7278-1764
Alberto BiancoDepartment of Chemistry "Giacomo Ciamician", University of Bologna, Bologna, Italy.ORCID https://orcid.org/0000-0001-9783-7955
Albert RuggiDepartment of Chemistry, University of Fribourg, Fribourg, Switzerland.ORCID https://orcid.org/0000-0003-2860-9080
Giacomo BergaminiDepartment of Chemistry "Giacomo Ciamician", University of Bologna, Bologna, Italy.ORCID https://orcid.org/0000-0002-2135-4073

Funding

European Union-NextGenerationEU CUP: B33C22000710006European Union-NextGenerationEU iENTRANCE@ENLEuropean Union-NextGenerationEU IR0000027Università di Bologna
6 · The paper itself

Abstract

Supramolecular control over electron transfer is a key challenge in artificial photosynthesis. Here, we report a cyano-bridged Ru-Fe supramolecular photocatalyst that self-assembles in solution through spontaneous coordination. This preorganized architecture enables ultrafast excited-state electron transfer from Ru to Fe via a static oxidative quenching pathway, as revealed by pump-probe transient absorption spectroscopy showing sub-picosecond formation of the reduced Fe species, in contrast to the reductive quenching mechanisms commonly observed in related systems. Remarkably, reversible coordination of CO

Indexed as

CO2 reductioncyanide bridgingelectron transferiron catalysissupramolecular photocatalysis

Identifiers

PMID42595742
PMCPMC13473391

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.