Development of a Ground-Based Hyperspectral Remote Sensing System for High-Frequency Monitoring of Riverine Organic Carbon.

Traditional approaches for monitoring aquatic organic carbon, such as satellite remote sensing and automated underwater sensors, are often constrained by limited temporal resolution, data gaps under cloudy conditions, maintenance requirements, and cost-effectiveness. To overcome these limitations, we developed and field-demonstrated a ground-based hyperspectral remote sensing system (GHRSS) for continuous, high-frequency monitoring of dissolved organic carbon (DOC) and particulate organic carbon (POC). The system is based on the above-water method and integrates three miniature hyperspectral spectrometers to measure water-surface radiance, sky radiance, and downwelling irradiance for deriving hyperspectral remote sensing reflectance (Rrs). The spectrometers cover 400-900 nm with a spectral resolution of 1 nm and support a minimum sampling interval of 10 s. The GHRSS also integrates solar power supply, 4G communication, and a microcomputer, enabling autonomous long-term deployment and wireless data transmission. Based on the GHRSS, retrieval models for DOC and POC were developed and validated using 90 paired in situ measurements collected from the Cao'e River. Empirical and machine learning methods were applied to retrieve DOC and POC from the measured Rrs data. The empirical models showed limited retrieval performance, whereas partial least squares regression (PLSR) and support vector regression (SVR) substantially improved model accuracy. Among all models, SVR achieved the best performance on the independent test set, with R2=0.979, RMSE = 0.031 mg/L, and MAE = 0.024 mg/L for DOC and R2=0.960, RMSE = 0.152 mg/L, and MAE = 0.066 mg/L for POC. Using the optimal SVR models, minute-scale time series of DOC and POC were reconstructed from the GHRSS observations. The results revealed pronounced sub-daily variability in both parameters, with DOC varying relatively smoothly, whereas POC exhibited stronger short-term fluctuations and more rapid responses to hydrodynamic changes. These findings demonstrate that the GHRSS, combined with machine learning models, provides an effective and practical approach for continuous, high-frequency monitoring of riverine organic carbon dynamics.