ArticleMaterials (Basel, Switzerland)2026
Spray Pyrolysis of Ternary Oxides: From Precursor Selection to Surface Reactions.
Article in Materials (Basel, Switzerland), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Spray pyrolysis is a popular method for the low-cost synthesis of oxides and other compounds in thin-film form. Here, we discuss several nuances of using this method for ternary and quaternary compounds. Specifically, we outline how precursor solubility and thermal decomposition, as well as desorption of intermediate species from the sample surface govern the spray pyrolysis growth process. We demonstrate how the stoichiometry transfer from solution to film can be affected in selected test cases. We present real-time optical growth measurements of the behaviour of individual Cu, Cr, Zn, and Sn precursors, as well as post-growth analysis of film composition by X-ray photoelectron spectroscopy for ternary transparent conducting oxides (TCOs; p-type: Cu
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