Evidence map›Paper›PMID 42585105›Full record

ArticleAngewandte Chemie (International ed. in English)2026

Short Sb···Sb Contacts in Polymorphic Tris(p-Tolyl)Antimony: A Hallmark of Organoantimony(III) Solid-State Chemistry?

Imogen Suh, Michael Ferguson, Filip Topić, Fu-Qiang Gong, Mihails Arhangelskis, Hatem M Titi, D Scott Bohle, Vinko Nemec, Levente Kiss, Andrew J Morris and 3 more

Abstract read
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In one paragraph

Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

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Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

13 authors.

Imogen SuhDepartment of Chemistry, McGill University, Montreal, Canada.ORCID https://orcid.org/0009-0001-0955-7433
Michael FergusonSchool of Chemistry, University of Birmingham, Edgbaston, UK.ORCID https://orcid.org/0000-0002-5479-1878
Filip TopićDepartment of Chemistry, McGill University, Montreal, Canada.ORCID https://orcid.org/0000-0003-3811-6036
Fu-Qiang GongSchool of Chemistry, University of Birmingham, Edgbaston, UK.ORCID https://orcid.org/0009-0008-7688-0901
Mihails ArhangelskisFaculty of Chemistry, University of Warsaw, Warsaw, Poland.ORCID https://orcid.org/0000-0003-1150-3108
Hatem M TitiDepartment of Chemistry, McGill University, Montreal, Canada.ORCID https://orcid.org/0000-0002-0654-1292
D Scott BohleDepartment of Chemistry, McGill University, Montreal, Canada.ORCID https://orcid.org/0000-0001-5833-5696
Vinko NemecDepartment of Chemistry, Faculty of Science, University of Zagreb, Zagreb, Croatia.ORCID https://orcid.org/0000-0001-7862-6888
Levente KissDepartment of Chemistry, Supramolecular Organic and Organometallic Chemistry Centre (SOOMCC), Faculty of Chemistry and Chemical Engineering, Babeș-Bolyai University, Cluj-Napoca, Romania.ORCID https://orcid.org/0000-0002-9811-5679
Andrew J MorrisSchool of Metallurgy and Materials, University of Birmingham, Edgbaston, UK.ORCID https://orcid.org/0000-0001-7453-5698
Cristian SilvestruDepartment of Chemistry, Supramolecular Organic and Organometallic Chemistry Centre (SOOMCC), Faculty of Chemistry and Chemical Engineering, Babeș-Bolyai University, Cluj-Napoca, Romania.ORCID https://orcid.org/0000-0001-5124-9525
Dominik CinčićDepartment of Chemistry, Faculty of Science, University of Zagreb, Zagreb, Croatia.ORCID https://orcid.org/0000-0002-4081-2420
Tomislav FriščićDepartment of Chemistry, McGill University, Montreal, Canada.ORCID https://orcid.org/0000-0002-3921-7915

Funding

Croatian Science Foundation IP-2025-02-6539European Union NextGenerationEU National Recovery and Resilience Plan 2021-2026Leverhulme International ProfessorshipMcGill UniversityNarodowe Centrum Nauki 2020/37/B/ST5/02638NSERC Discovery Grant JCP 562908-2022NSERC Discovery Grant RGPIN-2017-06467NSERC Discovery Grant RGPIN-2024-20456Tier-1 Canada Research Chair ProgramUniversity of BirminghamUniversity of Zagreb Faculty of Science NextGenChem Institutional grants
6 · The paper itself

Abstract

Discovery of a polymorph of tris(p-tolyl)antimony(III) reveals solid-state supramolecular dimers connected through short, attractive Sb∙∙∙Sb contacts that, based on theoretical calculations and a systematic screen of the Cambridge Structural Database (CSD), could be an overlooked hallmark of the solid-state and supramolecular chemistry of trivalent organoantimony(III) compounds. While the previously reported crystal structure of tris(p-tolyl)antimony(III) is known to exhibit phenyl embrace motifs, resembling the arsenic or phosphorus analogs, the new polymorph exhibits supramolecular dimers characterized by direct Sb∙∙∙Sb contacts shorter than the sum of the van der Waals radii, and stabilized by a significant dimer dissociation energy of ca. -26 kJ mol

Indexed as

antimonycrystal engineeringpolymorphismsupramolecularthermal analysis

Identifiers

PMID42585105
PMCPMC13638092

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.