ArticleJournal of fluorescence2026
Synthesis, Photophysical Investigation, and Nitroaromatic Sensing Properties of Novel Fused Pyrrolo[1,2-f]azolo[1,5-a]pteridines.
Article in Journal of fluorescence, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
A novel series of pyrrolo[1,2-f]azolo[1,5-a]pteridines has been synthesized via an efficient two-step annulation strategy. The photophysical properties of the resulting polyheteroaromatic fluorophores were systematically investigated in solution, solid state, and polymer films. In THF, the compounds exhibit intense emission in the visible region with high quantum yields (Ф up to 79.9%) and lifetimes of 10-13 ns. Solvatochromic studies reveal small positive solvatochromic shifts with increasing solvent polarity, and Lippert-Mataga analysis indicates a predominantly locally-excited (LE) state. While aggregation leads to quenching in the solid state, embedding in PVA films restores emission efficiency. The electron-rich scaffold shows pronounced fluorescence quenching in the presence of nitroaromatic analytes, including picric acid (PA) and 2,4-dinitrotoluene (DNT), with Stern-Volmer constants up to 9.2 × 10
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