ReviewFrontiers in chemistry2026
From surface terminations to functional nanoarchitectures: a chemistry-first framework for stabilizing and programming MXenes.
Review in Frontiers in chemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
MXenes combine metallic conductivity, solution processability, and chemically addressable surfaces, but the reactive interfaces that enable functionalization also accelerate oxidation, restacking, and property drift. This Mini Review develops a chemistry-first framework in which surface terminations, defects, adsorbates, and interlayer species are treated collectively as a coupled state variable rather than as independent descriptors. We link etching and delamination chemistry to termination populations and discuss the effects of water and oxygen on spatially heterogeneous degradation. We then examine how molecular ligands, polymers, inorganic phases, and mesoscale assembly modulate interfacial reactions and transport pathways. We organize recent studies according to a causal sequence: chemical intervention, nanoscale structural consequence, transport response, functional output, and failure mode. This sequence helps explain why nominally similar Ti
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