ArticleLangmuir : the ACS journal of surfaces and colloids2026
Effect of Surfactant Washing on the Readsorption Performance and Particle Durability of MOF-Coated Cotton Fabrics.
Article in Langmuir : the ACS journal of surfaces and colloids, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Metal-organic framework (MOF)-functionalized textiles have attracted considerable attention as advanced materials for protective clothing due to their high adsorption performance; however, their structural stability and performance recovery under surfactant-based laundering conditions remain poorly understood. In this study, the washing behavior of MIL-53(Fe)@cotton fabric was systematically investigated by examining the effects of surfactant types, temperatures, and mechanical forces on the readsorption performance of cationic rhodamine B (RhB) and anionic methyl orange (MO). Surfactant-assisted washing partially restored pore accessibility while preserving the framework structure. The readsorption behavior depended strongly on dye-specific interactions with surfactant-modified interfaces. In particular, linear alkylbenzenesulfonate (LAS) significantly improved the RhB readsorption, whereas its influence on MO was comparatively limited. Semiempirical calculations supported these observations, revealing pronounced surfactant-dependent changes in the adsorption energy on RhB but minor variations for MO. Among the mechanical regeneration methods examined, the laundering-o-meter treatment yielded the higest readsorption performance while better preserving the framework structure than stirring and ultrasonication. These findings elucidate the mechanism of surfactant-assisted washing in MOF-functionalized textiles and provide insights into maintaining their structural integrity and adsorption performance during practical laundering.
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