ArticleRSC advances2026
Direct and efficient Fischer-Tropsch synthesis on a defect-engineered cobalt-incorporated zirconium metal-organic framework.
Article in RSC advances, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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5 authors.
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Abstract
A defective metal-organic framework (MOF), UiO-66, was synthesized and functionalized with cobalt cations anchored directly to its Zr-oxo nodes. The resulting material, Co@DUiO-66, acts as a highly active catalyst for Fischer-Tropsch (FT) synthesis without requiring a pyrolysis step. In contrast to the standard practice of using pyrolyzed MOF derivatives, this work demonstrates the direct use of a metallated MOF for this reaction. Detailed characterization (TGA, DSC, FT-IR, EDX, elemental mapping, FESEM, XRD, ICP-OES, ICP-MS, CHN, TEM, and BET) confirms that the porosity is maintained and that cobalt remains uniformly dispersed at the atomic level. Under industrial conditions (220 °C, 20 bar, GHSV of 2400 mL g
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