ArticleMikrochimica acta2026
Pt nanoparticles-engineered metal-organic framework encapsulated by a covalent organic framework shell for self-powered photoelectrochemical sensing of carbendazim.
Article in Mikrochimica acta, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
To address the food safety risks caused by carbendazim (CBZ) residues, a high-efficiency self-powered photoelectrochemical (PEC) sensing platform was constructed for sensitive detection of CBZ. We present a PEC sensing interface based on a Pt nanoparticles-engineered ZIF-8 core encapsulated by a covalent organic framework (COF) shell (Pt NPs-ZIF-8@COF). Distinct Pt integration pathways were evaluated, revealing that in situ encapsulation of Pt NPs during ZIF-8 crystallization (Pt NPs-ZIF-8) mitigates particle aggregation and outperforms post-synthetic decoration of Pt NPs onto post-synthetic ZIF-8 (Pt NPs/ZIF-8). The COF overlayer further tailors the interfacial microenvironment by establishing a continuous charge-transport network, which together accelerate photogenerated charge separation and interfacial electron-transfer processes. Benefiting from these synergistic features, the resulting PEC sensor enables quantitative CBZ determination over a wide linear range from 1.0 × 10
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