Evidence map›Paper›PMID 42545189›Full record

ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2026

Local Solvent Ordering Drives Supramolecular Chirality Inversion.

Triza Pal, Akta Singh, Subinoy Adhikari, Jagannath Mondal, Debangshu Chaudhuri

Abstract read
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In one paragraph

Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Triza PalDepartment of Chemical Sciences, Indian Institute of Science Education and Research (IISER), Kolkata, India.
Akta SinghTata Institute of Fundamental Research, Hyderabad, Telangana, India.
Subinoy AdhikariTata Institute of Fundamental Research, Hyderabad, Telangana, India.
Jagannath MondalTata Institute of Fundamental Research, Hyderabad, Telangana, India.
Debangshu ChaudhuriDepartment of Chemical Sciences, Indian Institute of Science Education and Research (IISER), Kolkata, India.ORCID https://orcid.org/0000-0002-8941-4327

Funding

CSIR-IndiaDepartment of Atomic Energy, Government of India RTI 4007IISER Kolkata
6 · The paper itself

Abstract

Solvent composition is widely assumed to influence supramolecular chirality indirectly through bulk properties such as polarity or solvophobicity. Here, we show that local solvent organization can directly dictate chiral pathway selection and invert supramolecular helicity. A chiral perylene bisimide bearing L-phenylalanine substituents (L-PhePBI) undergoes a complete reversal of helical sense in water/DMSO mixtures upon a narrow change in solvent composition (Δf

Indexed as

chemistrydiimidehelicityhydrogen  bondmolecular dynamicperylenesolvation  shellsolvophobicsupramolecular chemistry

Identifiers

PMID42545189
PMCPMC13430924

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.