ArticleChemphyschem : a European journal of chemical physics and physical chemistry2026
Effect of Solvent Hydrogen-Bonding and Catalyst Pore Size on Catalytic Oxidation of Benzylic Alcohols.
Article in Chemphyschem : a European journal of chemical physics and physical chemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Control over selective oxidation rates remain a key challenge in industrial chemicals production. Here, we demonstrate how liquid phase alcohol oxidation is a complex interplay among solvent, reactant, catalyst porosity, and local active site environment. Specifically, we study the impact of sulfolane versus acetonitrile solvents on rates of catalytic oxidation of benzylic alcohols to the corresponding ketone using hydrogen peroxide (H
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