ArticleChemistry of materials : a publication of the American Chemical Society2026
A Bis(arenesulfonyl) Peroxide, an Ambient-Stable Oxidant, Is a Strong p‑Dopant for Organic Semiconductors.
Article in Chemistry of materials : a publication of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Strong p-dopants are required to dope high-ionization energy organic semiconductors for a variety of potential applications, but strong, simple one-electron oxidants are typically sensitive to reduction by atmospheric moisture and thus challenging to store or handle. Here we show that bis-(3,5-bis-(trifluoromethyl)-benzenesulfonyl) peroxidea dimer formed by two highly oxidizing radicalscan function as a water-stable yet powerful oxidant, cleanly reacting with some organic semiconductors to form two radical cations and two 3,5-bis-(trifluoromethyl)-benzenesulfonate anions, although in other cases sulfonylation reactions can also occur. Notably, this peroxide is capable of p-doping the high-ionization energy polymer poly-[(9,9-dioctylfluorene-2,7-diyl)-
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