ArticlePolymer science & technology (Washington, D.C.)2026
Phosphoryl-ene Step-Growth Polymerization: A Route to Polyphosphinates.
Article in Polymer science & technology (Washington, D.C.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Phosphorus-containing polymers have found wide application. Consequently, their synthesis is of great interest. Existing methods, however, primarily afford polyphosphonates and polyphosphates. Herein, we report a step-growth ″phosphoryl-ene″ polymerization strategy for incorporating phosphinate directly into the polymer backbone. Readily accessible AB-type phosphoryl monomers undergo radical step-growth polyaddition to yield the target polyphosphinates. Furthermore, AA-type bis-phosphoryl monomers can be used in radical step-growth polymerization with dienes or anionic step-growth polymerization with di-esters. This strategy provides an unprecedented and versatile approach to phosphorus-containing polymers, opening promising possibilities for polyphosphinate-based functional materials.
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