Twisted amide Xantphos ligands: wide bite angle, twist-controlled diphosphines.

Wenchao Chu, Tongliang Zhou, Guangchen Li, Elwira Bisz, Błażej Dziuk, Roger Lalancette, Roman Szostak, Michal Szostak

Abstract read

In one paragraph

Article in Chemical communications (Cambridge, England), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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0citing papers in PubMed

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1 · What the graph read from it

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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

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3 · Its place in the literature

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0 citing papers in PubMed.

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4 · The record

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5 · Who and what money

Authors and funding

8 authors.

Wenchao ChuDepartment of Chemistry, Rutgers University, 73 Warren Street, Newark, NJ 07102, USA. michal.szostak@rutgers.edu.ORCID http://orcid.org/0000-0002-7815-0514

Tongliang ZhouDepartment of Chemistry, Rutgers University, 73 Warren Street, Newark, NJ 07102, USA. michal.szostak@rutgers.edu.ORCID http://orcid.org/0000-0002-7334-7078

Guangchen LiDepartment of Chemistry, Rutgers University, 73 Warren Street, Newark, NJ 07102, USA. michal.szostak@rutgers.edu.

Elwira BiszDepartment of Chemistry and Pharmacy, University of Opole, 48 Oleska Street, Opole 45-052, Poland.ORCID http://orcid.org/0000-0002-7070-2468

Błażej DziukDepartment of Chemistry, Wroclaw University of Science and Technology, Norwida 4/6, Wroclaw 50-373, Poland.

Roger LalancetteDepartment of Chemistry, Rutgers University, 73 Warren Street, Newark, NJ 07102, USA. michal.szostak@rutgers.edu.ORCID http://orcid.org/0000-0002-3470-532X

Roman SzostakDepartment of Chemistry, Wroclaw University, F. Joliot-Curie 14, Wroclaw 50-383, Poland.ORCID http://orcid.org/0000-0002-5436-7284

Michal SzostakDepartment of Chemistry, Rutgers University, 73 Warren Street, Newark, NJ 07102, USA. michal.szostak@rutgers.edu.ORCID http://orcid.org/0000-0002-9650-9690

Funding

Catalytic Methods for Organic SynthesisR35GM133326 · NIGMS · RUTGERS THE STATE UNIV OF NJ NEWARK · PI Michal Szostak · 2019 to 2026

$2.7M

NIGMS NIH HHS R35 GM133326

6 · The paper itself

Abstract

Xantphos ligands are among the most significant bis(phosphines) developed in the field of homogeneous catalysis. Twisted amides have been established to have a pronounced impact on the geometry of substituents attached to the amide linkage. Herein, we describe the synthesis, structural characterization and activity of novel, easily accessible twisted amide Xantphos ligands. These ligands feature controlled P-P distances and increased P-M-P bite angles guided by the amide bond twist and geometry. Notably,

Identifiers

PMID42533815

DOI10.1039/d6cc02815b

PMCPMC13430992

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.