Silicon-Bridged Homocyclopentadienides: Metal-Assisted Facile Ring Expansion of Cyclopentadienide by Transient Imino(Metallophosphino)Silylenes.

Huaiyuan Zhu, Xufang Liu, Shicheng Dong, Jun Zhu, Shigeyoshi Inoue

Abstract read

In one paragraph

Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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0cells of the map it votes in

0citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

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0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

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5 · Who and what money

Authors and funding

5 authors.

Huaiyuan ZhuTUM School of Natural Sciences, Department of Chemistry, Catalysis Research Center and Chair of Silicon Chemistry, Technische Universität München (TUM), Garching bei München, Germany.ORCID https://orcid.org/0009-0003-4084-9172

Xufang LiuTUM School of Natural Sciences, Department of Chemistry, Catalysis Research Center and Chair of Silicon Chemistry, Technische Universität München (TUM), Garching bei München, Germany.

Shicheng DongSchool of Chemistry and Chemical Engineering, Guangxi Colleges and Universities Key Laboratory of Applied Chemistry Technology and Resource Development, Guangxi University, Nanning, Guangxi, China.

Jun ZhuGuangdong Basic Research Center of Excellence for Aggregate Science, School of Science and Engineering, The Chinese University of Hong Kong, Shenzhen, Guangdong, China.ORCID https://orcid.org/0000-0002-2099-3156

Shigeyoshi InoueTUM School of Natural Sciences, Department of Chemistry, Catalysis Research Center and Chair of Silicon Chemistry, Technische Universität München (TUM), Garching bei München, Germany.ORCID https://orcid.org/0000-0001-6685-6352

Funding

European Union's Horizon ALLOWE101001591

6 · The paper itself

Abstract

In this study, we report the aromatic C─C bond cleavage of cyclopentadienide by transient imino(metallophosphino)silylenes through the reaction of silylene equivalents with CpCo(CO)

Indexed as

aromatic C─C bond activationcyclopentadienidehomoaromaticityphosphasilenesilylene

Identifiers

PMID42530301

DOI10.1002/anie.6837297

PMCPMC13618273

What OpenQuestion holds

Textmetadata

Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.