ArticleAdvanced materials (Deerfield Beach, Fla.)2026
Ternary Cooperative Interface With Electronegative Phosphine Bridges Enables Efficient and Stable Inverted Perovskite Solar Cells.
Pingping Ma, Yiting Zheng, Ziyue Zhang, Shijing Qian, Xin Zhao, Yingdong Xia, Yonghua Chen
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In one paragraphArticle in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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7 authors.
Pingping MaState Key Laboratory of Flexible Electronics (LoFE) and Institute of Advanced Materials (IAM), School of Flexible Electronics (Future Technologies), Nanjing Tech University (Nanjing Tech), Nanjing, Jiangsu, China.
Yiting ZhengState Key Laboratory of Flexible Electronics (LoFE) and Institute of Advanced Materials (IAM), School of Flexible Electronics (Future Technologies), Nanjing Tech University (Nanjing Tech), Nanjing, Jiangsu, China.
Ziyue ZhangState Key Laboratory of Flexible Electronics (LoFE) and Institute of Advanced Materials (IAM), School of Flexible Electronics (Future Technologies), Nanjing Tech University (Nanjing Tech), Nanjing, Jiangsu, China.
Shijing QianState Key Laboratory of Flexible Electronics (LoFE) and Institute of Advanced Materials (IAM), School of Flexible Electronics (Future Technologies), Nanjing Tech University (Nanjing Tech), Nanjing, Jiangsu, China.
Xin ZhaoState Key Laboratory of Flexible Electronics (LoFE) and Institute of Advanced Materials (IAM), School of Flexible Electronics (Future Technologies), Nanjing Tech University (Nanjing Tech), Nanjing, Jiangsu, China.
Yingdong XiaState Key Laboratory of Flexible Electronics (LoFE) and Institute of Advanced Materials (IAM), School of Flexible Electronics (Future Technologies), Nanjing Tech University (Nanjing Tech), Nanjing, Jiangsu, China.ORCID https://orcid.org/0000-0003-4023-3231 Yonghua ChenState Key Laboratory of Flexible Electronics (LoFE) and Institute of Advanced Materials (IAM), School of Flexible Electronics (Future Technologies), Nanjing Tech University (Nanjing Tech), Nanjing, Jiangsu, China.ORCID https://orcid.org/0000-0002-9694-4246 Funding
Basic Research Program of Jiangsu Province BK20243057Fundamental and Interdisciplinary Disciplines Breakthrough Plan JYB2025XDXM406Jiangsu Funding Program for Excellent Postdoctoral Talent 2025ZB133Jiangsu Provincial Department of Science and Technology BE2022023Jiangsu Provincial Department of Science and Technology BK20220010Jiangsu Provincial Department of Science and Technology BK20241875Jiangsu Provincial Department of Science and Technology BZ2023060Ministry of Education of ChinaNational Key Research and Development Program of China 2023YFB4204500National Natural Science Foundation of China 22379067National Natural Science Foundation of China 62288102National Natural Science Foundation of China U24A20568Open Research Fund of Suzhou Laboratory SZLAB-13082024-ZD006Postdoctoral Fellowship Program of CPSF GZC20250577Shanghai Synchrotron Radiation Facility
6 · The paper itselfAbstract
Carbazole-based self-assembled monolayers (SAMs) are widely used in high-performance perovskite solar cells (PSCs); however, single-component SAMs often suffer from incomplete coverage on FTO substrates and weak interactions with the perovskite layer, leading to interfacial defects and crystallization stress. Herein, we develop a synergistic interface engineering strategy by introducing a phosphine-based molecule, bis(4-trifluoromethylphenyl)(4-carboxyphenyl)phosphine (TFMP), to construct a ternary cooperative interface (Co-SAM@TFMP) based on a co-adsorbed self-assembled monolayer (Co-SAM) composed of [4-(3,6-dimethyl-9H-carbazol-9-yl)butyl]phosphonic acid (Me-4PACz) and [4-(9'-phenyl-9H,9'H-[3,3'-bicarbazol]-9-yl)butyl]phosphonic acid (4PABCz). In this system, the phosphonic and carboxylic acid groups are firmly anchored to the substrate, improving the integrity of the interfacial coverage. At the buried interface, TFMP acts as a molecular bridge by coordinating with Pb
Indexed as
cooperative interface engineeringcrystallization stress regulationdefect passivationinverted perovskite solar cellsself‐assembled monolayers
Identifiers
PMID42529961
PMCPMC13579078
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