Evidence map›Paper›PMID 42529593›Full record

ArticleJACS Au2026

Adaptive Zinc-Amide Catalysis Enables C(sp

Subarna Manna, Navya Shenny Kavil, Arnab Rit

Abstract read
In one paragraph

Article in JACS Au, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Subarna MannaDepartment of Chemistry, Indian Institute of Technology Madras, Chennai 600036, India.
Navya Shenny KavilDepartment of Chemistry, Indian Institute of Technology Madras, Chennai 600036, India.
Arnab RitDepartment of Chemistry, Indian Institute of Technology Madras, Chennai 600036, India.ORCID https://orcid.org/0000-0003-0224-8387

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Developing sustainable and efficient catalytic strategies to construct aryl alkyl ethers from inexpensive feedstocks remains a central objective in modern synthetic chemistry. In this context, a ligand-centered redox-controlled zinc amide system is disclosed herein that enables highly selective defluoroetherification of aryl fluorides, irrespective of their electronic nature, with diverse alcohols under mild conditions (70-80 °C, 4-8 h), for the first time. Comprehensive mechanistic studies, including radical-trapping experiments, EPR spectroscopy, HRMS analysis, and various control experiments, support a radical-mediated C-(sp

Indexed as

C2-amidated azolium saltC−F bond activationdefluoroetherificationradical pathwayzinc compound

Identifiers

PMID42529593
PMCPMC13417243

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC-ND
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.