ArticleJACS Au2026
Programming Structural Flexibility for Tunable Gas Sorption via Hydrogen Bonding in Polyoxometalate-Based Porous Ionic Crystals.
Article in JACS Au, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Porous ionic crystals (PICs) are porous molecular solids assembled through nondirectional Coulomb interactions, whose inherent structural flexibility during guest sorption and desorption creates adaptive pore environments that lead to unconventional gas sorption and separation selectivity. Although such flexibility is expected to be reflected in both thermodynamics and kinetic aspects of guest sorption, these two viewpoints have rarely been examined together. Herein, we apply a crystal engineering approach based on noncovalent intermolecular interactions to systematically tune the flexibility of PICs constructed from triol-ligand-modified (
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