ArticleSmall (Weinheim an der Bergstrasse, Germany)2026
Potential-Dependent Reversible Restructuring of Pt-Au Alloy Electrocatalysts.
Article in Small (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The distribution of metals in alloy nanoparticles is a key parameter in their electrochemical performance. Here, we show that for Pt-Au alloys this distribution dynamically responds to the electrochemical environment. Using electrochemical X-ray photoelectron spectroscopy, we find that the surface composition of the alloy can range from stoichiometric to Pt-enriched, depending on the applied potential. The driving factors for this restructuring are the differences in electronegativity and mobility between Pt and Au. At potentials below 1.5 V
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