ArticleThe journal of physical chemistry. C, Nanomaterials and interfaces2026
Uncovering Correlations between Structure and Valence Tautomerism in Cobalt-o-Dioxolene Crystals.
Article in The journal of physical chemistry. C, Nanomaterials and interfaces, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Bistability in transition-metal complexes can originate from several phenomena, including mixed valence (MV), spin-crossover (SCO), and valence tautomerism (VT). In the latter case, valence-tautomeric interconversion (VTI) generates pairs of switchable redox isomers whose physical properties can be controlled by external stimuli, such as light, temperature, and pressure, making these systems promising candidates for molecular devices, spintronics, and chemosensing. Although several strategies exist to modulate VTI in crystalline materials, tuning intermolecular interactions has emerged as a particularly effective route. In cobalt-o-dioxolene complexes of the type [Co-(dioxolene)
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