ReviewMolecules (Basel, Switzerland)2026
Functionalized Nitrile Oxides and Their Synthetic Equivalents: Recent Advances in Generation Methods and Synthetic Applications.
Review in Molecules (Basel, Switzerland), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Functionalized nitrile oxides have attracted increasing attention because the incorporated functional groups not only influence cycloaddition reactivity but also provide valuable handles for subsequent molecular diversification. Despite their considerable synthetic potential, however, the development of practical methods for generating functionalized nitrile oxides has remained challenging because suitable precursors are often difficult to access and many functional groups are incompatible with conventional generation conditions. Consequently, only a limited number of reliable precursor systems have been established. This review summarizes recent advances in the generation of nitrile oxides bearing synthetically valuable acyl, ester, amide, and cyano functionalities, together with the development of synthetic equivalents that circumvent the intrinsic instability of these reactive intermediates. Particular emphasis is placed on 2-methyl-4-nitroisoxazoline-5(2
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