Evidence map›Paper›PMID 42509592›Full record

ArticleChemphyschem : a European journal of chemical physics and physical chemistry2026

Hydrogen Spillover in Isotopic Exchange Reaction.

Yurii A Zolotarev, Eduard V Bocharov, Yurii A Borisov, Alexander K Dadayan, Yaroslav V Bershatsky, Igor Yu Nagaev, Nikolay F Myasoedov

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Article in Chemphyschem : a European journal of chemical physics and physical chemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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0citing papers in PubMed
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1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

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Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Yurii A ZolotarevNRC «Kurchatov Institute», Moscow, Russia.
Eduard V BocharovShemyakin-Ovchinnikov Institute of Bioorganic Chemistry of Russian Academy of Science, Moscow, Russia.
Yurii A BorisovA.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russia.
Alexander K DadayanNRC «Kurchatov Institute», Moscow, Russia.
Yaroslav V BershatskyShemyakin-Ovchinnikov Institute of Bioorganic Chemistry of Russian Academy of Science, Moscow, Russia.
Igor Yu NagaevNRC «Kurchatov Institute», Moscow, Russia.
Nikolay F MyasoedovNRC «Kurchatov Institute», Moscow, Russia.

Funding

Russian Ministry of Science and Higher Education 075-15-2025-461
6 · The paper itself

Abstract

The high-temperature solid-phase catalytic isotope exchange (HSCIE) reaction in organic compounds, which occurs with the participation of hydrogen spillover (SH), was studied experimentally and with DFT B3LYP and MP2 calculations. The HSCIE reaction yielded deuterium-labeled [D]estradiol, containing, on average, about 7 deuterium atoms per molecule. The isotope distribution and the experimental value of the reaction activation energy were determined using NMR spectroscopy and mass spectroscopy. Using DFT B3LYP, the HSCIE reaction mechanism was studied. The reaction mechanism can be represented as a synchronous one-center mechanism of hydrogen exchange between estradiol adsorbed on the surface of an inorganic substrate and a model charged aluminum oxide cluster, HH

Indexed as

hydrogen spilloverNMR spectroscopyquantum chemistryreaction mechanismsolid‐phase catalytic reaction

Identifiers

PMID42509592
PMCPMC13408199

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