Evidence map›Paper›PMID 42506581›Full record

ArticleOrganic letters2026

Photocatalytic Decyanative Borylation of Dicyanoarenes Enabled by Radical-Radical Coupling.

Naoki Yasukawa, Ryota Nomura, Waka Okada, Kazutake Takada, Tsunayoshi Takehara, Takeyuki Suzuki, Daniele Leonori, Shuichi Nakamura

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Organic letters, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Naoki YasukawaDepartment of Life Science and Applied Chemistry, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya, Aichi466-8555, Japan.ORCID 0000-0002-7994-0470
Ryota NomuraDepartment of Life Science and Applied Chemistry, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya, Aichi466-8555, Japan.
Waka OkadaDepartment of Life Science and Applied Chemistry, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya, Aichi466-8555, Japan.
Kazutake TakadaDepartment of Life Science and Applied Chemistry, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya, Aichi466-8555, Japan.
Tsunayoshi TakeharaThe Institute of Scientific and Industrial Research, Osaka University, 8-1 Mihogaoka, Ibaraki-shi, Osaka567-0047, Japan.ORCID 0000-0002-4113-7578
Takeyuki SuzukiThe Institute of Scientific and Industrial Research, Osaka University, 8-1 Mihogaoka, Ibaraki-shi, Osaka567-0047, Japan.ORCID 0000-0002-2137-0276
Daniele LeonoriInstitute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52056Aachen, Germany.ORCID 0000-0002-7692-4504
Shuichi NakamuraDepartment of Life Science and Applied Chemistry, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya, Aichi466-8555, Japan.ORCID 0000-0001-5633-8367

Funding

Amano Institute of Technology NAJapan Society for the Promotion of Science JP24K17678Japan Society for the Promotion of Science JP26K17848Research Foundation for the Electrotechnology of Chubu NATokuyama Science Foundation NA
6 · The paper itself

Abstract

Cyanoarenes are important scaffolds in pharmaceutical and materials science and serve as versatile building blocks in synthetic chemistry. Herein, we report an orthogonal strategy for the decyanative borylation of dicyanoarenes via radical-radical coupling between amine-ligated boryl radicals and dicyanoarene-derived radical anions, enabled by an oxidative quenching photoredox cycle. Importantly, the resulting amine-borane adducts readily engage in Suzuki-Miyaura cross-couplings with aryl halides, including late-stage functionalization of bioactive compounds.

Identifiers

PMID42506581
PMCPMC13459413

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.