ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2026
Phonon-Driven Tetrahedral Tilts Enable Ultralow Bulk Thermal Expansion and Interstitial Oxide-Ion Migration in Phenacite Solid Electrolytes.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Oxide-ion solid electrolytes are enabling components for high-temperature electrochemical technologies, including batteries, fuel cells, membrane reactors, sensors, and electrolyzers. The long-standing challenge is the thermal-expansion-coefficients (TECs) mismatch between electrolytes and adjacent device components over broad operating temperature windows. Here, we demonstrate a design paradigm of phonon-driven negative-thermal-expansion (NTE) framework can be leveraged not only to suppress thermal expansion but also to activate interstitial oxide-ion migration through collective tetrahedral tilts. As a proof of concept, we report the first demonstration of interstitial oxide-ion conduction in La-doped flexible phenacite-type NTE Zn
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