ArticleOrganic letters2026
Synthesis and Reactions of Hydrazine Trifluoroborate Salts.
Article in Organic letters, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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5 authors.
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Abstract
We report a new class of hydrazine trifluoroborate salts that undergo chemoselective reactions to deliver a range of new functionalized building blocks for organic synthesis. In particular, we show that a wide range of pyrazole N-methylboronates can be prepared by condensation reactions with 1,3-dicarbonyl compounds and conjugated ynones with high regiocontrol. Finally, the synthetic potential of these pyrazole derivatives is demonstrated by SEAr, three-component alkyl Petasis Boron-Mannich reaction, and through the synthesis of palovarotene analogs.
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