ArticleSmall (Weinheim an der Bergstrasse, Germany)2026
Switching Urea Oxidation Reaction Pathways by Regulating Multi-Component Sites on Chlorine-Doped Nickel-Cobalt Hydroxides.
Article in Small (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Urea oxidation reaction (UOR) has been considered as a promising alternative to the oxygen evolution reaction for hydrogen production. So far, there are two proposed catalytic reaction alternatives for UOR, including a conventional direct six-electron process and a rarely reported two-stage reaction pathway. Herein, we successfully achieved the switching of UOR pathways by artificially increasing/decreasing the concentration of oxygen vacancies monotonously on nickel-cobalt hydroxides. The "multi-component active sites" and the UOR structural-pathway relation were clearly elucidated by extensive experimental characterizations and density functional theory (DFT) calculations. With rich "multi-component active sites", chlorine-substituted nickel-cobalt hydroxides (NiCoClOH) exhibit a record performance for Ni
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