Evidence map›Paper›PMID 42497014›Full record

ArticlePhysical chemistry chemical physics : PCCP2026

Vibrational spectra of formic acid and its dimer: II. Towards identifying structural motifs in atmospheric organic clustering.

Dennis F Dinu, Vincent Enders, Julius Stolze, Lukas Meinschad, Jonas Schlagin, Klaus R Liedl, Guntram Rauhut, Thomas Loerting, Hinrich Grothe, Maren Podewitz and 1 more

Abstract read
In one paragraph

Article in Physical chemistry chemical physics : PCCP, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

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3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Dennis F DinuInstitute of Materials Chemistry, TU Wien, Getreidemarkt 9, 1060 Wien, Austria. dominik.stolzenburg@tuwien.ac.at.ORCID http://orcid.org/0000-0001-8239-7854
Vincent EndersInstitute of Materials Chemistry, TU Wien, Getreidemarkt 9, 1060 Wien, Austria. dominik.stolzenburg@tuwien.ac.at.ORCID http://orcid.org/0009-0004-4228-7609
Julius StolzeInstitute of Materials Chemistry, TU Wien, Getreidemarkt 9, 1060 Wien, Austria. dominik.stolzenburg@tuwien.ac.at.ORCID http://orcid.org/0009-0002-7704-0003
Lukas MeinschadDepartment of General, Inorganic and Theoretical Chemistry, University of Innsbruck, Innrain 80, 6020 Innsbruck, Austria.ORCID http://orcid.org/0009-0004-5919-6201
Jonas SchlaginInstitute of Materials Chemistry, TU Wien, Getreidemarkt 9, 1060 Wien, Austria. dominik.stolzenburg@tuwien.ac.at.ORCID http://orcid.org/0009-0002-8734-7519
Klaus R LiedlDepartment of General, Inorganic and Theoretical Chemistry, University of Innsbruck, Innrain 80, 6020 Innsbruck, Austria.ORCID http://orcid.org/0000-0002-0985-2299
Guntram RauhutInstitute of Theoretical Chemistry, University of Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany.ORCID http://orcid.org/0000-0003-0623-3254
Thomas LoertingDepartment of Physical Chemistry, University of Innsbruck, Innrain 52, 6020 Innsbruck, Austria.ORCID http://orcid.org/0000-0001-6694-3843
Hinrich GrotheInstitute of Materials Chemistry, TU Wien, Getreidemarkt 9, 1060 Wien, Austria. dominik.stolzenburg@tuwien.ac.at.ORCID http://orcid.org/0000-0002-2715-1429
Maren PodewitzInstitute of Materials Chemistry, TU Wien, Getreidemarkt 9, 1060 Wien, Austria. dominik.stolzenburg@tuwien.ac.at.ORCID http://orcid.org/0000-0001-7256-1219
Dominik StolzenburgInstitute of Materials Chemistry, TU Wien, Getreidemarkt 9, 1060 Wien, Austria. dominik.stolzenburg@tuwien.ac.at.ORCID http://orcid.org/0000-0003-1014-1360

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

This work constitutes part II of a series on vibrational spectroscopy of formic acid, focusing on the molecular interactions of its carboxyl group during dimerization. Such interactions drive the earliest steps of clustering in organic-mediated atmospheric new particle formation (NPF), and are difficult to access with the mass spectrometric methods typically used to study NPF. While theoretical thermochemistry provides binding free energies for various cluster conformers, these conformers have not been experimentally probed to date, and it is unclear which conformers ultimately participate in atmospheric organic clustering. Vibrational spectroscopy using matrix-isolation provides a route to experimentally investigate the conformers of small clusters. To identify simple conformers in the clustering of the carboxyl group, we use the model system of the formic acid monomer and dimer in cryogenic matrices in combination with

Identifiers

PMID42497014
PMCPMC13398933

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