ArticleACS omega2026
High-Flux Halloysite Nanotube-Reinforced PVDF Membranes with Zwitterionic Coating for One-Step Separation of Complex Oil-Water Emulsions.
Article in ACS omega, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Authors and funding
7 authors.
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Abstract
Industrial oily wastewater containing heavy metal ions threatens ecosystems and human health, and developing high-flux multifunctional membranes for their simultaneous removal is a critical challenge. Herein, a high-flux multifunctional polyvinylidene fluoride composite membrane, HNTs/PVDF@PDA/PSBMA, was fabricated by blending halloysite nanotubes (HNTs) into the PVDF matrix via nonsolvent-induced phase separation (NIPS), followed by surface modification with a polydopamine (PDA)/poly-(sulfobetaine methacrylate) (PSBMA) zwitterionic coating. HNTs introduced one-dimensional water channels via inner/outer surface hydroxyl groups to boost water flux and provide active sites for heavy metal adsorption, while the PDA/PSBMA coating formed a robust hydration layer through electrostatic interactions with water molecules, endowing excellent antifouling and underwater oleophobicity as well as additional heavy metal adsorption capacity. Under optimized conditions (1.0 wt % HNTs, 2.0 mg/mL PSBMA), the HNTs/PVDF@PDA/PSBMA membrane exhibited a drastically enhanced water flux of 528.6 L·m
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