ArticleiScience2026
Electrochemical synthesis of Cu-pyrene MOF and its outstanding pohotoelectrocatalytic activity in hydrogen evolution reaction.
Article in iScience, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
A new procedure based on bipolar electrochemistry (BPE) is proposed for the synthesis of a copper-pyrene framework (Cu-py MOF). Accordingly, BPE using Cu mesh as BP electrode between two stainless steel driving electrodes is performed for 150 min under an applied potential of 3.0 V in acetonitrile containing 5% of 0.1 M NaOH aqueous solution. After characterization, the resulting compound is utilized for HER in water at electrolyte-free condition. Interestingly, the photocatalytic water reduction at the resulting material starts at 0.64 V relative to RHE, and photocurrent is increased with sweeping of potential in the cathodic direction, where the current density at an applied potential of 0.3 V vs. RHE reaches ∼30 μA cm
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