ArticleAngewandte Chemie (International ed. in English)2026
Proton Conduction in Stable, Crystalline, and Porous Hydrogen-Bonded Metal-Organic Frameworks.
Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Hydrogen-bonded metal-organic frameworks (HMOFs) represent a novel class of crystalline materials that integrate hydrogen bonds (HBs) and coordination bonds (CBs) within stable structures. Herein, we designed carbonyl-rich molecules with extended arms to increase the density of hydrogen-bond acceptors and enhanced benzene ring rotation to reduce π-π stacking, thereby strengthening hydrogen bonding to assist coordination-driven assembly of HMOFs. Benefiting from strong hydrogen bonding between central carbonyl groups and metal ions to modulate metal coordination, a series of 2+2 layer-interpenetrated HMOFs with different metal nodes (Co
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