ArticleAdvanced materials (Deerfield Beach, Fla.)2026
Decoupled Catalysis in Lithium-Oxygen Batteries: Directed Oxygen-Species Spillover Between Dual Single-Atoms to Circumvent Linear Scaling Limit.
Article in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Oxygen species spillover across sites in heterogeneous catalysis is a core strategy for reconfiguring reaction pathways and overcoming the theoretical limits of the Sabatier volcano plot. The key lies in achieving thermodynamic decoupling and kinetic synergy in multi-step reactions. Based on Hard-Soft Acid-Base (HSAB) theory, this study constructs a series of Co-based Ln (Sm, Eu, Gd, Tb, and Dy) dual single-atom catalytic systems (CoLn-DAC) through selective coordination design, serving as model platforms to decouple the fundamental electron-transfer steps in electrochemical reactions. Directional oxygen species spillover is captured at the dual-single-atom scale: oxygen-philic Ln sites activate O
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