ArticleAdvanced materials (Deerfield Beach, Fla.)2026
Construction of Multiply Bridged Coordination Framework via a Cluster-Ligand Strategy.
Article in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
In the context of reticular chemistry, linking secondary building units (SBUs) through multiple bridging modes could enhance structural robustness and facilitate the development of versatile frameworks. However, the deliberate synthesis of coordination frameworks by these multiply bridged SBUs remains challenging, as the component SBUs are typically generated in situ during framework assembly. Here, we report facile synthesis of a multiply bridged coordination framework via a cluster-ligand strategy, where pre-functionalized metal nanoclusters (NCs) with high-density coordination sites are used as multi-bridging linkers to transition metal cluster nodes. Specifically, a predesigned [Au
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