Evidence map›Paper›PMID 42484538›Full record

ArticleAdvanced materials (Deerfield Beach, Fla.)2026

Controlled Synthesis and Interfacial Bonding of Hexagonal Diamond/Wurtzite Boron Nitride Covalent Heterostructures.

Lu Bai, Jiayin Li, Jiaxin Ming, Yuguo Chen, Wenhongxin Li, Pengcheng Zhao, Jiangnan Song, Tiansong Zhang, Wuxiao Han, Guoshuai Du and 5 more

Abstract read
In one paragraph

Article in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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1 · What the graph read from it

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2 · The registry

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3 · Its place in the literature

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4 · The record

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5 · Who and what money

Authors and funding

15 authors.

Lu BaiSchool of Interdisciplinary Science, Beijing Institute of Technology, Beijing, China.ORCID https://orcid.org/0009-0005-6193-7205
Jiayin LiSchool of Interdisciplinary Science, Beijing Institute of Technology, Beijing, China.
Jiaxin MingSchool of Interdisciplinary Science, Beijing Institute of Technology, Beijing, China.
Yuguo ChenSchool of Interdisciplinary Science, Beijing Institute of Technology, Beijing, China.
Wenhongxin LiSchool of Interdisciplinary Science, Beijing Institute of Technology, Beijing, China.
Pengcheng ZhaoSchool of Interdisciplinary Science, Beijing Institute of Technology, Beijing, China.ORCID https://orcid.org/0009-0003-7383-7848
Jiangnan SongSchool of Interdisciplinary Science, Beijing Institute of Technology, Beijing, China.
Tiansong ZhangSchool of Interdisciplinary Science, Beijing Institute of Technology, Beijing, China.
Wuxiao HanSchool of Interdisciplinary Science, Beijing Institute of Technology, Beijing, China.
Guoshuai DuSchool of Interdisciplinary Science, Beijing Institute of Technology, Beijing, China.ORCID https://orcid.org/0000-0001-8902-4196
Kenji WatanabeResearch Center for Electronic and Optical Materials, National Institute for Materials Science, Tsukuba, Japan.ORCID https://orcid.org/0000-0003-3701-8119
Takashi TaniguchiResearch Center for Materials Nanoarchitectonics, National Institute for Materials Science, Tsukuba, Japan.ORCID https://orcid.org/0000-0002-1467-3105
Jian-Guo ZhangState Key Laboratory of Explosion Science and Safety Protection, Beijing Institute of Technology, Beijing, China.ORCID https://orcid.org/0000-0001-7057-2862
Tiange BiSchool of Interdisciplinary Science, Beijing Institute of Technology, Beijing, China.ORCID https://orcid.org/0000-0001-5866-190X
Yabin ChenSchool of Interdisciplinary Science, Beijing Institute of Technology, Beijing, China.ORCID https://orcid.org/0000-0002-5180-2009

Funding

CREST JPMJCR24A5JSPS KAKENHI 21H05233JSPS KAKENHI 23H02052JSTNational Natural Science Foundation of China 12090031National Natural Science Foundation of China 52072032National Natural Science Foundation of China 52472040World Premier International Research Center Initiative
6 · The paper itself

Abstract

Heterostructures, mediated by either weak van der Waals (vdW) coupling or chemical bonding at the heterointerface, can compensate for the inherent shortcomings of individual components and achieve exotic properties through their effective integration. The isoelectronic diamond and boron nitride (BN) can present both cubic and wurtzite polymorphs and hence prospectively form diverse heterostructures. However, synthesizing the metastable hexagonal diamond/wurtzite BN (HD/wBN) covalent heterostructures and clarifying the interfacial chemical bonds remain great challenges, despite considerable effort. In this study, we have demonstrated the direct synthesis of high-quality HD/wBN covalent heterostructures via structural transformation of graphite/hBN vdW heterostructures under high pressure and high temperature. Raman and structural characterizations evidently confirmed the sharp HD/wBN heterointerface with both C─B and C─N bonds, attributed to inversion domain boundaries within the wBN phase. The mapped pressure-temperature diagram exhibited the confined window required for HD/wBN heterostructures. Our work provides a viable pathway to prepare various covalent heterostructures through synergistic phase transitions and opens new opportunities for exploring their pronounced properties.

Indexed as

boron nitridecovalent heterostructuresdiamonddiamond anvil cellhigh pressure and high temperatureinterfacial bonds

Identifiers

PMID42484538
PMCPMC13532458

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