ReviewAdvanced materials (Deerfield Beach, Fla.)2026
From Metal-Centered Catalysis to Organic Orbital Programming in Photoelectrocatalysis.
Review in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Authors and funding
10 authors.
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Abstract
Photoelectrocatalysis has traditionally relied on inorganic metals and compounds, where activity is optimized through crystal field regulation, band alignment, and defect engineering. However, periodic lattice structures intrinsically constrain orbital degeneracy, energy-level reconstruction, and molecular-scale control of intermediate adsorption, electron transfer, and reaction flux. Purely organic photoelectrocatalytic materials offer a distinct paradigm based on π-conjugated frameworks, in which frontier orbitals, energy-level splitting, electron delocalization, and polarization can be precisely programmed through molecular design. Donor-acceptor architectures, orbital overlap, and electronic asymmetry regulate exciton binding, charge separation, interfacial coupling, and intermediate electronic occupation, thereby linking photocarrier dynamics directly with reaction barriers and pathway selection. In water splitting, CO
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.