ArticleNature chemistry2026
A photogenerated triplet aura-nitrene for gold-mediated nitrene transfer.
Article in Nature chemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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6 authors.
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Abstract
The isolation and characterization of metal-stabilized, low-valent nitrogen species remain central challenges in advancing nitrogen-atom transfer chemistry. Although gold has emerged as a powerful catalyst in C-N bond formation, proposed mechanisms have consistently bypassed gold nitrenes as key intermediates-leaving their chemistry largely uncharted. Here we report the characterization of a bona fide aura-nitrene, formed via photochemical N
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