ArticleAdvanced materials (Deerfield Beach, Fla.)2026
Vertical Through‑Bond Co─O─Mo Bridge Enables Dual‑Site Nonradical Selective Oxidation.
Article in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Selective oxidation via nonradical pathways is crucial for broad-ranged catalytic applications, yet it remains difficult to construct catalytic interfaces that efficiently activate oxidants while stabilize reactive intermediates at solid-liquid boundary for driving nonradical reactions. Conventional planar or quasi-planar interface-engineering strategies mainly tune local coordination environments or macroscopic phase contacts, and fail to couple two dissimilar redox centers at the atomic scale. Here, we propose the construction of asymmetric Co─O─Mo bridges at a buried interface to enable the formation of a vertical through-bond interface that preferentially catalyze nonradical reactions. Specifically, the bridging oxygen connects a CoOOH overlayer and a defect-rich MoS
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