Evidence map›Paper›PMID 42478513›Full record

ArticleSmall methods2026

Unveiling 4d (Ru)-5d (Pt) Charge Compensation for Li-Oxygen/Air Batteries With Ultralow Overpotentials.

Jialin Chen, Jinglin Yang, Luhai Gai, Xuanhao Liu, Deliang Cui, Qilong Wang, Feng Dang, Haohai Yu, Gang Lian

Abstract read
In one paragraph

Article in Small methods, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

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3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Jialin ChenState Key Lab of Crystal Materials, Shandong University, Jinan, People's Republic of China.
Jinglin YangSchool of Materials Science and Engineering, Shandong University, Jinan, People's Republic of China.
Luhai GaiState Key Lab of Crystal Materials, Shandong University, Jinan, People's Republic of China.
Xuanhao LiuState Key Lab of Crystal Materials, Shandong University, Jinan, People's Republic of China.
Deliang CuiState Key Lab of Crystal Materials, Shandong University, Jinan, People's Republic of China.
Qilong WangKey Laboratory for Special Functional Aggregated Materials of Education Ministry, School of Chemistry & Chemical Engineering, Shandong University, Jinan, People's Republic of China.
Feng DangSchool of Materials Science and Engineering, Shandong University, Jinan, People's Republic of China.ORCID https://orcid.org/0000-0002-8038-5398
Haohai YuState Key Lab of Crystal Materials, Shandong University, Jinan, People's Republic of China.ORCID https://orcid.org/0000-0002-2295-1400
Gang LianState Key Lab of Crystal Materials, Shandong University, Jinan, People's Republic of China.ORCID https://orcid.org/0000-0001-5459-8819

Funding

National Natural Science Foundation of China 51972197Natural Science Foundation of Shandong Province ZR2023ZD12
6 · The paper itself

Abstract

Lithium-oxygen batteries hold great promise for next-generation energy storage systems due to their ultrahigh theoretical energy density. However, their development is hindered by high charging overpotentials and poor cycle stability. Herein, we propose a strategy of electronic structure regulation to design a Ru-modified Pt/C catalyst to address the key challenge of tuning the charge overpotential. Electron delocalization occurs from Ru to Pt in RuPt because of the electronegativity difference between Ru and Pt. The calculation results show that the 4d(Ru)-5d(Pt) orbital coupling regulates the d-band distribution of Pt sites in RuPt, including the moderate downshift of d-band center systematically across the Pt's five d-suborbitals and the broadening of d-band above the Fermi energy level. It weakens the adsorption strength towards oxygen-containing species and smooths the energy barriers of stepwise reactions during OER. Experimental results demonstrate that the Ru-Pt/C catalyst significantly reduces the overpotential by ∼1 V compared to Pt/C. Meanwhile, the Li-air battery also presents a low overpotential of 0.75 V after 100 cycles. This work advances the fundamental understanding of d-band regulation via engineering electronic structure in oxygen electrocatalysis and provides a practical pathway to mitigate overpotential-related challenges in high-energy-density metal-air batteries.

Indexed as

charge compensationd‐band regulationLi‐oxygen batteriesoverpotentialsRuPt nanodots

Identifiers

PMID42478513
PMCPMC13505691

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.