ArticleAdvanced materials (Deerfield Beach, Fla.)2026
A Current-Adaptive Polyoxovanadates Protected Anode for Efficient and Stable Ampere-Level Seawater Electrolysis.
Article in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Seawater electrolysis is promising for green hydrogen production, while intensified chloride corrosion at high-current density (HCD) poses significant challenges to the activity and stability of the anodes. Conventional anode catalysts leverage anion electrostatic repulsion to repel chloride but often fail under industrially relevant ampere-level HCD conditions, restricting their applications. Here we report a corrosion-resistant cobalt-vanadium-oxide catalyst featuring in situ formed, current-adaptive polyoxovanadates (POVs) for efficient and stable seawater electrolysis at HCD. As the current densities increase, the vanadate monomers dynamically self-assemble into POVs with significantly increased steric hindrance to Cl
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