ArticleSmall (Weinheim an der Bergstrasse, Germany)2026
Carbon-Driven Interfacial Molecular Enrichment Strategy for Efficient Electrooxidation of 5-Hydroxymethylfurfural.
Article in Small (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The electrochemical oxidation of HMF to FDCA represents an attractive strategy for biomass valorization. However, sluggish reaction kinetics caused by insufficient adsorption and activation of HMF molecules at catalyst interfaces remains a major challenge. Herein, we report a PdNiO/C composite catalyst in which Pd nanoparticles and NiO are integrated on a conductive carbon matrix for efficient HMF electrooxidation. The PdNiO/C catalyst exhibits a low onset potential (1.10 V vs. RHE) and achieves high FDCA yield and FE (>90%) with excellent electrochemical stability. Mechanistic investigations reveal that the carbon matrix induces an interfacial molecular enrichment effect through π-π interactions, which significantly increases the local concentration of HMF molecules near catalytic sites. Meanwhile, Pd facilitates the oxidation of Ni
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