ArticleACS applied materials & interfaces2026
Low-Voltage Resistive Switching and Synaptic Plasticity in Cs2AgBiBr6 Memristors.
Article in ACS applied materials & interfaces, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Synaptic devices that can store and process data are imperative to mimic the operation of the human brain. In this work, lead-free double perovskite Cs2AgBiBr6 memristors were fabricated on ITO/glass substrates with thermally evaporated Ag top electrodes and systematically investigated for their resistive switching (RS) and neuromorphic functionalities. The devices exhibit stable, low-voltage (+0.239 ± 0.018 V) volatile resistive switching with good cycle-to-cycle reproducibility. A maximum ON/OFF ratio exceeding 105 is maintained for 24 cycles, while values above 102 persist for 1100 cycles. Electrical analysis reveals that the switching behavior is governed by ion migration-induced filament formation, primarily involving mobile Br- ions, VBr+ vacancies, and Ag+ ions injected from the electrode. A detailed conduction model is proposed based on space charge-limited conduction and ion-induced electric field screening. Furthermore, the volatile RS characteristics enable biologically inspired synaptic functions, including spike amplitude-dependent plasticity (SADP), spike number-dependent plasticity (SNDP), and paired-pulse facilitation (PPF) with a maximum facilitation index of 169%, benchmarking competitively among perovskite memristive synapses. Based on experimentally extracted synaptic weight-update rules, an artificial neural network simulation achieved a peak recognition accuracy of 98%.
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