ArticleAdvanced materials (Deerfield Beach, Fla.)2026
A Fluorine-Free Solvent Based on Dual Descriptors for Ultrawide-Temperature Lithium Metal Batteries (-105°C to 70°C).
Article in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Fluorinated solvents are widely employed in electrolytes for lithium metal batteries (LMBs) due to their broad liquid-phase temperature range. However, their use entails significant challenges, including undesirable interfacial parasitic reactions at elevated temperatures and lithium-salt precipitation at low temperatures. In this study, we propose a fluorine-free electrolyte design strategy based on synergistic optimization of molecular geometry and electron density distribution. The tailored solvent, 2-ethylbutyl acetate (2EA), plays a critical role in modulating intermolecular interactions and Li
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