ArticleOrganic letters2026
Orthogonal Triple-Click Synthesis of Heteromimetic Triglycosylated Fullerenes.
Article in Organic letters, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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6 authors.
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Abstract
Well-defined heteromultivalent glycoarchitectures remain challenging synthetic targets. Herein we report a [60]fullerene hexakis-adduct platform designed to undergo three orthogonally addressable click reactions, allowing the controlled conjugation of three distinct carbohydrates within a single nanostructure. The approach combines thiol-maleimide coupling with two sequential CuAAC transformations using protected and unprotected alkyne handles and supports both stepwise functionalization and one-pot reaction sequences. NMR and DOSY experiments confirmed the integrity and homogeneity of the resulting triple-functionalized glycofullerenes.
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