ArticleChemistry of materials : a publication of the American Chemical Society2026
Pd-Cu Single-Atom Catalysts in Covalent Organic Frameworks for Sonogashira Cross-Coupling Reaction.
Article in Chemistry of materials : a publication of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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6 authors.
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Abstract
Bimetallic single-atom catalysts containing two distinct metals within well-defined and spatially controlled environments can offer cooperative reactivity. Here, we present a versatile design strategy for constructing metallophthalocyanine covalent organic frameworks (COFs) containing precisely engineered Pd and Cu sites through mixed-metal ionothermal synthesis, followed by wet impregnation. The corresponding COF, named Pd-Cu@pyPPC-NaCl, is synthesized through the polymerization of tetracyanopyrazine in a molten salt mixture of CuCl
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